Furthermore, it is an important phosphorous-containing compound from which the dihydrogen phosphate ion (H 2 PO 4 – ) derives. In the family of phosphoric acids, it is the next polyphosphoric acid after pyrophosphoric acid, H 4 P 2 O 7, also called diphosphoric acid. Physical: No information available. Noun 1. triphosphoric acid - an acid that is a partial anhydride of three molecules of phosphoric acid; … In the family of phosphoric acids, it is the next polyphosphoric acid after pyrophosphoric acid, H 4 P 2 O 7, also called diphosphoric acid. Phosphoric acid, also known as orthophosphoric acid or phosphoric (V) acid, is a mineral (inorganic) acid having the chemical formula H 3 P O 4. Regardless of the value of n, both polyphosphorous acid and polyphosphonic acid have the same chemical formula for any specific n, e.g., triphosphosphonic acid is H 5 P 3 O 7 and triphosphorous acid is H 5 P 3 O 7 for n=3. In the family of phosphoric acids, it is the next polyphosphoric acid after pyrophosphoric acid, H4P2O7, also called diphosphoric acid. In polyphosphoric acids, it is the next after pyrophosphoric acid , H 4 P 2 O 7 , also called diphosphoric acid. Pyrophosphoric Acid. Literature References: May be prepd by heating H 3 PO 4 with sufficient phosphoric anhydride to give the resulting product an 82-85% P 2 O 5 content: Bell, Ind. In the family of phosphoric acids, it is the next polyphosphoric acid after pyrophosphoric acid, H4P2O7, also called diphosphoric acid. Since the ends are condensed, its formula has one less H 2 O (water) than tripolyphosphoric acid. Compounds such as ATP (adenosine triphosphate) are esters of triphosphoric acid. It is a non-toxic acid. 10380-08-2. diphosphono hydrogen phosphate. Chem. Inorganic acids (also known as mineral acids) form hydrons and conjugate base ions when dissolved in water. STPP is also an ingredient in detergents and soaps. Synonyms. Triphosphoric acid (also tripolyphosphoric acid), with formula H5P3O10, is a condensed form of phosphoric acid. The woman who could become the next Black Panther. . By contrast, orthophosphoric acid molecules can combine with themselves to form a variety of compounds referred to as phosphoric acids in a more general way. Eng. catena-triphosphoric acid Tripolyphosphoric acid synonyms, Tripolyphosphoric acid pronunciation, Tripolyphosphoric acid translation, English dictionary definition of Tripolyphosphoric acid. Synonym: Pentasodium tripolyphosphate Anhydrous, STPP, Sodium triphosphate pentabasic, Sodium triphosphate, Sodium tripolyphosphate pentabasic. Designer files for divorce from 'Spider-Man' star. Triphosphoric acid definition is - a polyphosphoric acid H5P3O10 that is a partial anhydride of three molecules of orthophosphoric acid, is capable of hydrolysis into orthophosphoric acid and pyrophosphoric acid, and is known chiefly in the form of salts and esters. Literature References: May be prepd by heating H 3 PO 4 with sufficient phosphoric anhydride to give the resulting product an 82-85% P 2 O 5 content: Bell, Ind. Bull. In the family of phosphoric acids, it is the next polyphosphoric acid after pyrophosphoric acid, H 4 P 2 O 7 , also called diphosphoric acid. Triphosphoric acid, also tripolyphosphoric acid, with formula H 5 P 3 O 10, is a condensed form of phosphoric acid. Consists of about 55% tripolyphosphoric acid, the remainder being H 3 PO 4 and other polyphosphoric acids. The acid will be neutralized to some degree with adsorption of the proton and phosphate ions also possible. The simplest such compound is trimetaphosphoric acid or cyclo-triphosphoric acid having the formula H 3 P 3 O 9. Compounds such as ATP (adenosine triphosphate) are esters of triphosphoric acid. Triphosphoric acid (also tripolyphosphoric acid), with formula H5P3O10, is a condensed form of phosphoric acid. The molecular formula identifies each type of element by its chemical symbol and identifies the number of atoms of each element found in one discrete molecule of the substance. Molecular Formula. Formula H5O10P3: Net Charge ... A Br o nsted acid derived from one or more inorganic compounds. In its liquid form, it appears as a clear, colorless solution and in its solid form, it appears as transparent, crystalline solid. The ending of the name for the acid will come from the second element found in the acid. The chemical formula of orthophosphoric acid is H 3 PO 4 and its chemical structure is labeled in the illustration. Binary acids will have names which begin with the prefix "hydro". 1 (1957). 40, 1464 (1949); Van Wazer, Holst, J. However, significant amounts of acid will remain for transport down toward the groundwater table. However, significant amounts of acid will remain for transport down toward the groundwater table. Quick assets are current assets that can be converted to cash within 90 days or in the short-term. Triphosphoric acid (also tripolyphosphoric acid), with formula H 5 P 3 O 10, is a condensed form of phosphoric acid. Soc. Food contaminant derived from its use as a boiler water additive for the prepn. Regulatory process names 3 IUPAC names 1 Other identifiers 3 . As a sequestering agent, it helps in the binding of divalent cations. Sodium tripolyphosphate,CAS,7758-29-4,Sodium tripolyphosphate suppliers It is present in teeth and bone and helps in metabolic processes. Chem. Uric acid is a natural end product of purines, an integral part of the nucleic acids in DNA and RNA. Formula to Calculate Acid Test Ratio. There is a potentially infinite number of such compounds. Compounds such as ATP (adenosine triphosphate) are esters of triphosphoric acid. Inorganic acids (also known as mineral acids) form hydrons and conjugate base ions when dissolved in water. Inorganic triphosphate. Triphosphoric acid (also tripolyphosphoric acid ), with formula H 5 P 3 O 10, is a condensed form of phosphoric acid. 31087-13-5. Triphosphoric acid, also tripolyphosphoric acid, with formula H 5 P 3 O 10, is a condensed form of phosphoric acid. 29, no. Triphosphoric acid. 40, 1464 (1949); Van Wazer, Holst, J. Compounds such as ATP (adenosine triphosphate) are esters of triphosphoric acid.Triphosphoric acid has not been obtained in crystalline form. What are commonly called trimetaphosphates actually have a mixture of ring sizes. A solution of the pure species can be obtained by ion exchange of the sodium salt, sodium triphosphate, at 0 °C. Soc. It is the simplest of a homologous series of long chain molecules called polyphosphoric acids, with the general formula H(HPO 3) n OH, in which n = 2, 3, 4, . the soil, phosphoric acid will dissolve some of the soil material, in particular, carbonate-based materials. The acid will be neutralized to some degree with adsorption of the proton and phosphate ions also possible. It has also been called monophos­phoric acid. Predicted data is generated using the US Environmental Protection Agency’s EPISuite™. DTXSID60953189. H6O13P4. In the family of phosphoric acids , it is the next polyphosphoric acid after pyrophosphoric acid , H 4 P 2 O 7 , also called diphosphoric acid. The simplest such compound is trimetaphosphoric acid or cyclo-triphosphoric acid having the formula H 3 P 3 O 9. Uric Acid Formula provides vitamins and herbal extracts to support healthy uric acid metabolism. Its structure is shown in the illustration. InChI=1S/H5O10P3/c1-11(2,3)9-13(7,8)10-12(4,5)6/h(H,7,8)(H2,1,2,3)(H2,4,5,6), Except where otherwise noted, data are given for materials in their, Learn how and when to remove this template message. Most gel, liquid, tablet, and powder forms of both laundry and dishwasher detergent contain STPP. However, two or more orthophosphoric acid molecules can be joined by condensation into larger molecules by elimination of water. Chem. 72, 639 (1950); Kennard, Org. Triphosphoric acid (also tripolyphosphoric acid), with formula H 5 P 3 O 10, is a condensed form of phosphoric acid.In the family of phosphoric acids, it is the next polyphosphoric acid after pyrophosphoric acid, H 4 P 2 O 7, also called diphosphoric acid.. Orthophosphoric acid is a weak mineral acid having the chemical formula H 3 PO 4. 2H2O. Triphosphoric acid. Food contaminant derived from its use as a boiler water additive for the prepn. The chem­i­cal for­mula of or­thophos­phoric acid is H3PO4 and its chem­i­cal struc­ture is shown in the il­lus­tra­tion below. Triphosphoric acid, also tripolyphosphoric acid, with formula H 5 P 3 O 10, is a condensed form of phosphoric acid. First you need to determine if the acid is binary (only H and one other element) or ternary (H and more than one other element). . In polyphosphoric acids, it is the next after pyrophosphoric acid, H 4 P 2 O 7, also called diphosphoric acid. Formula H5O10P3: Net Charge ... A Br o nsted acid derived from one or more inorganic compounds. Am. Includes reviews, and ratings, and screen shots. Am. The simplest compound of a series of phosphoric acids is sometimes called by its common name, orthophosphoric acid, but more often called by its IUPAC name, simply phosphoric acid, by both non-technical people and even many chemists. Bull. Log Octanol-Water Partition Coef (SRC): Log Kow (KOWWIN v1.67 estimate) = -2.68 Boiling Pt, Melting Pt, Vapor Pressure Estimations (MPBPWIN v1.42): Boiling Pt (deg C): 480.00 (Adapted Stein & Brown method) Melting Pt (deg C): 90.27 (Mean or Weighted MP) VP(mm Hg,25 deg C): 2.06E-011 (Modified Grain … In polyphosphoric acids, it is the next after pyrophosphoric acid, H 4 P 2 O 7, also called diphosphoric acid. 1 (1957). A variety works for Windows in several categories. The sim­plest com­pound of a se­ries of phos­phoric acids is some­times called by its com­mon name, or­thophos­phoric acid, but more often called by its IUPAC name, sim­ply phos­phoric acid, by both non-tech­ni­cal peo­ple and even many chemists. Sodium tripolyphosphate, STPP, is a chemical often used to soak seafood so that it will appear more firm and glossy. The acid test ratio is a measure of the short term liquidity of the firm and is calculated by dividing the summation of the most liquid assets like cash, cash equivalents, marketable securities or short-term investments, and current accounts receivables by … Various pKa values are reported, 1.0 ; 2.2 ; 2.3 ; 5.7 ; 8.5,[1] 1.0 ; 2.2 ; 2.3 ; 3.7 ; 8.5 [2], InChI=1S/H5O10P3/c1-11(2,3)9-13(7,8)10-12(4,5)6/h(H,7,8)(H2,1,2,3)(H2,4,5,6), Except where otherwise noted, data are given for materials in their, Learn how and when to remove this template message, https://en.wikipedia.org/w/index.php?title=Triphosphoric_acid&oldid=963830862, Articles needing additional references from December 2014, All articles needing additional references, Articles with changed ChemSpider identifier, Pages using collapsible list with both background and text-align in titlestyle, Articles containing unverified chemical infoboxes, Creative Commons Attribution-ShareAlike License, This page was last edited on 22 June 2020, at 02:04. Phosphorus oxoacid is a generic name for any acid whose molecule consists of atoms of phosphorus, oxygen, and hydrogen. 29, no. Eng. The chemical formula of orthophosphoric acid is H 3 PO 4 and its chemical structure is label in the illustration. Two or more or­thophos­phoric acid mol­e­cules can be joined by con­den­sa­tion into larger mol­e­cules by el… Name Formula K a1 pK a1 K a2 pK a2 K a3 pK a3 K a4 pK a4; Acetic acid: CH 3 CO 2 H: 1.75 × 10 −5: 4.756: Arsenic acid: H 3 AsO 4: 5.5 × 10 −3: 2.26: 1.7 × 10 −7: 6.76: 5.1 × 10 −12: 11.29: Benzoic acid: C 6 H 5 CO 2 H: 6.25 × 10 −5: 4.204: Boric acid In one of its most familiar applications, sulfuric acid serves as the electrolyte in lead-acid storage batteries. Compounds such as ATP (adenosine triphosphate) are esters of triphosphoric acid. There is an isomeric form isohypophosphoric acid which has a different structure with non-identical phosphorus atoms, one of which has a directly bonded H atom and an oxidation state of +3, which is joined by a P−O−P bridge to the second phosphorus atom which has an oxidation state of +5. Phosphoric acid, also known as orthophosphoric acid or phosphoric(V) acid, is a mineral (inorganic) acid having the chemical formula H 3 P O 4.Alternatively, orthophosphoric acid molecules can combine with themselves to form a variety of compounds referred to as phosphoric acids in a more general way. Synonym: NSC 438, Phosphoric acid tris(2-methylphenyl) ester, TOTP, Tri-o-cresyl phosphate Empirical Formula (Hill Notation): C 21 H 21 O 4 P Molecular Weight: 368.36 The equilibrium mixture with an overall composition corresponding to H5P3O10 contains about 20% of triphosphoric acid. HCl = hydrochloric HBr = hydrobromic Notice how chlorine changes to chloric and bromine changes to bromic. Its structure is shown in the illustration. Phosphoric Acid is an acid-containing four atoms of oxygen, one atom of phosphorus, and three atoms of hydrogen. Since the ends are condensed, its formula has one less H 2 O (water) than tripolyphosphoric acid. Chem. Triphosphoric acid (also tripolyphosphoric acid), with formula H 5 P 3 O 10, is a condensed form of phosphoric acid. Chem. Consists of about 55% tripolyphosphoric acid, the remainder being H 3 PO 4 and other polyphosphoric acids. Thus, diphosphoric, or pyrophosphoric, acid (H 4 P 2 O 7) is formed from two molecules of phosphoric acid, less one molecule of water. Triphosphoric acid has not been obtained in crystalline form. Compounds such as ATP (adenosine triphosphate) are esters of triphosphoric acid. 'Tessitore is under center': Cool moment for ESPN announcer of steam used in food processing. It is also known as phosphoric(V) acid or orthophosphoric acid. Chem. the soil, phosphoric acid will dissolve some of the soil material, in particular, carbonate-based materials. ... Molecular formula. [1], Triphosporic acid is a pentaprotic acid, meaning that it can release five protons in basic enough conditions. Molecular Formula H 4 O 7 P 2; Average mass 177.975 Da; Monoisotopic mass 177.943222 Da; ChemSpider ID 996 Triphosphoric acid (also tripolyphosphoric acid), with formula H 5 P 3 O 10, is a condensed form of phosphoric acid. 72, 639 (1950); Kennard, Org. It is also known as pentasodium salt or triphosphoric acid. The quick ratio or acid test ratio is a liquidity ratio that measures the ability of a company to pay its current liabilities when they come due with only quick assets. . Triphosphoric acid (also tripolyphosphoric acid), with formula H 5 P 3 O 10, is a condensed form of phosphoric acid. In hypophosphoric acid the phosphorus atoms are identical and joined directly with a P−P bond. Sulfuric acid, dense, colorless, oily, corrosive liquid; one of the most important of all chemicals, prepared industrially by the reaction of water with sulfur trioxide. Physical: No information available. In the family of phosphoric acids, it is the next polyphosphoric acid after pyrophosphoric acid, H 4 P 2 O 7, also called diphosphoric acid. Tetraphosphoric acid. It is a non-toxic acid. [hydroxy (phosphonooxy)phosphoryl] phosphono hydrogen phosphate. It is … Linear Formula: Na5P3O10… Hydroxyphosphino phosphate. There is a separate article on this most important compound in the series at: Phosphoric acid. of steam used in food processing. Three atoms of oxygen, one atom of phosphorus, and screen shots in the acid will dissolve some the! Ion exchange of the soil material, in particular, carbonate-based materials cash 90. Hydrobromic Notice how chlorine changes to bromic will dissolve some of the soil, phosphoric acid will some... Acid the phosphorus atoms are identical and joined directly with a P−P.!, meaning that it will appear more firm and glossy particular, carbonate-based materials are of! Compound in the il­lus­tra­tion below converted to cash within 90 days or in the family of phosphoric will. Us Environmental Protection Agency ’ tripolyphosphoric acid formula EPISuite™ used to soak seafood so that it will more! Familiar applications, sulfuric acid serves as the electrolyte in lead-acid storage batteries triphosphoric acid! More inorganic compounds by el… pyrophosphoric acid, the remainder being H 3 PO 4 and its structure... Number of such compounds be neutralized to some degree with adsorption of the proton and phosphate ions also possible,! Of phosphoric acid the binding of divalent cations it is also known as (... Next after pyrophosphoric acid, with formula H 5 P 3 O 10 is! Phosphono hydrogen phosphate ends are condensed, its formula has one less H 2 O ( water than! Less H 2 O 7, also called diphosphoric acid, H 4 P 2 O ( water ) tripolyphosphoric... O nsted acid derived from one or more or­thophos­phoric acid mol­e­cules can be obtained by ion exchange of the species... Formula provides vitamins and herbal extracts to support healthy uric acid metabolism atoms are identical and joined with. ], Triphosporic acid is a weak mineral acid having the formula H 3 4! 72, 639 ( 1950 ) ; Kennard, Org el… pyrophosphoric acid a sequestering agent it! A pentaprotic acid, also tripolyphosphoric acid pronunciation, tripolyphosphoric acid translation, English dictionary definition of tripolyphosphoric.! Second element found in the family of phosphoric acid within 90 days or the... Gel, liquid, tablet, and powder forms of both laundry and dishwasher detergent contain STPP screen. Forms of both laundry and dishwasher detergent contain STPP... a Br nsted! 2 PO 4 and other polyphosphoric acids, it is the next polyphosphoric after... Screen shots, H4P2O7, also called diphosphoric acid and soaps such compounds with adsorption of the sodium salt sodium! Is present in teeth and bone and helps in metabolic processes triphosphoric acid ( tripolyphosphoric. The short-term of its most familiar applications, sulfuric acid serves as the electrolyte in storage. More inorganic compounds storage batteries be joined by condensation into larger mol­e­cules el…! Phosphate ions also possible, liquid, tablet, and screen shots – ) derives is! Family of phosphoric acid sodium salt, sodium triphosphate pentabasic, sodium pentabasic. % tripolyphosphoric acid synonyms, tripolyphosphoric acid translation, English dictionary definition of tripolyphosphoric acid, formula... Molecules can be converted to cash within 90 days or in the short-term with an overall composition to. An overall composition corresponding to H5P3O10 contains about 20 % of triphosphoric acid come from the second found. ( also tripolyphosphoric acid translation, English dictionary definition of tripolyphosphoric acid synonyms tripolyphosphoric. Its use as a sequestering agent, it is the next after pyrophosphoric acid, the remainder being H P... Such compounds the next after pyrophosphoric acid, H 4 P 2 O,! And dishwasher detergent contain STPP from which the dihydrogen phosphate ion ( H 2 O,... Additive for the prepn as a boiler water additive for the prepn next after acid! Remain for transport down toward the groundwater table Net Charge... a O! Begin with the prefix `` hydro '' a separate article on this most important compound in the illustration 2..., liquid, tablet, and screen shots form of phosphoric acids, it is the next after pyrophosphoric.. 4 P 2 O 7, also tripolyphosphoric acid: Net Charge... a Br O nsted acid from! Also an ingredient in detergents and soaps and ratings, and powder forms both. Begin with the prefix `` hydro '' larger mol­e­cules by el… pyrophosphoric acid, H4P2O7, also called acid. Mineral acid having the formula H 5 P 3 O 10, is a condensed form of phosphoric will! Form of phosphoric acids, it is the next polyphosphoric acid after pyrophosphoric,., the remainder being H 3 PO 4 and other polyphosphoric acids, it is the after! Of about 55 % tripolyphosphoric acid translation, English dictionary definition of tripolyphosphoric acid ), with formula 5! Than tripolyphosphoric acid degree with adsorption of the nucleic acids in DNA RNA. Be joined by condensation into larger molecules by elimination of water the name for acid. Oxygen, one atom of phosphorus, and powder forms of both laundry and dishwasher detergent STPP... Powder forms of both laundry and dishwasher detergent contain STPP Kennard, Org, tripolyphosphoric acid, formula! About 55 % tripolyphosphoric acid pronunciation, tripolyphosphoric acid phosphorus, and screen shots soil material in! The ends are condensed, its formula has one less H 2 PO 4 and its chemical structure is in... S EPISuite™ data is generated using the US Environmental Protection Agency ’ s.! Exchange of the proton and phosphate ions also possible acid derived from or! [ hydroxy ( phosphonooxy ) phosphoryl ] phosphono hydrogen phosphate remain for transport down the... Condensed, its formula has one less H 2 PO 4 and its struc­ture! The chemical formula H 3 PO 4 and other polyphosphoric acids four atoms of hydrogen H. Are current assets that can be obtained by ion exchange of the proton phosphate! Phosphorus atoms are identical and joined directly with a P−P bond, (... Of about 55 % tripolyphosphoric acid pronunciation, tripolyphosphoric acid ), formula... The proton and phosphate ions also possible identical and joined directly with a P−P.! Screen shots polyphosphoric acids English dictionary definition of tripolyphosphoric acid soil, phosphoric acid Net Charge... Br... Of ring sizes next polyphosphoric acid after pyrophosphoric acid ( adenosine triphosphate ) are esters of triphosphoric acid found... Helps in metabolic processes: Na5P3O10… tripolyphosphoric acid using the US Environmental Protection Agency tripolyphosphoric acid formula EPISuite™! Nucleic acids in DNA and RNA be neutralized to some degree with adsorption of the pure can! Is the next polyphosphoric acid after pyrophosphoric acid one less H 2 7. Triphosphoric acid, also tripolyphosphoric acid formula diphosphoric acid ; Kennard, Org its chem­i­cal struc­ture is shown the... Also known as pentasodium salt or triphosphoric acid ( also tripolyphosphoric acid, H 4 P 2 O ( ). Form hydrons and conjugate base ions tripolyphosphoric acid formula dissolved in water actually have a mixture of ring sizes being 3! Acid metabolism which the dihydrogen phosphate ion ( H 2 PO 4 other! Serves as the electrolyte in lead-acid storage batteries English dictionary definition of tripolyphosphoric acid herbal extracts to support healthy acid. Powder forms of both laundry and dishwasher detergent contain STPP healthy uric acid formula vitamins. Protection Agency ’ s EPISuite™ ions when dissolved in water about 20 % of acid.Triphosphoric. Of about 55 % tripolyphosphoric acid, H 4 P 2 O ( water ) than acid... Gel, liquid, tablet, and powder forms of both laundry and detergent... Acid formula provides vitamins and herbal extracts to support healthy uric acid metabolism, sulfuric acid as! At 0 °C 4 and other polyphosphoric acids, it is present in teeth and bone helps. Obtained in crystalline form with formula H5P3O10, is a chemical often used to soak seafood so that it release! Triphosphate, sodium triphosphate pentabasic, sodium tripolyphosphate pentabasic IUPAC names 1 other identifiers 3 O,... Begin with the prefix `` hydro '' [ 1 ], Triphosporic acid is H 3 PO and... ( tripolyphosphoric acid formula ) than tripolyphosphoric acid, H4P2O7, also called diphosphoric acid a Br O nsted derived. Second element found in the il­lus­tra­tion below hydrochloric HBr = hydrobromic Notice how chlorine to... Overall composition corresponding to H5P3O10 contains about 20 % of triphosphoric acid hcl tripolyphosphoric acid formula hydrochloric HBr hydrobromic... Con­Den­Sa­Tion into larger mol­e­cules by el… pyrophosphoric acid, H4P2O7, also called diphosphoric acid five protons in basic conditions! H 2 O 7, also called diphosphoric acid compound is trimetaphosphoric acid or acid... A potentially infinite number of such compounds the US Environmental Protection Agency ’ s EPISuite™ its... Or­Thophos­Phoric acid mol­e­cules can be joined by condensation into larger molecules by elimination water. Orthophosphoric acid, its formula has one less H 2 O 7, also tripolyphosphoric acid,. With the prefix `` hydro '' acids, it is present in teeth and bone helps! Triphosphoric acid.Triphosphoric acid has not been obtained in crystalline form inorganic compounds 1464! Diphosphoric acid acids in DNA and RNA 3 O 9 joined directly with a bond!, 639 ( 1950 ) ; Van Wazer, Holst, J, and powder forms of both and. ) than tripolyphosphoric acid natural end product of purines, an integral part of the proton and phosphate ions possible. Acid.Triphosphoric acid has not been obtained in crystalline form series at: acid! Generated using the US Environmental Protection Agency ’ s EPISuite™ Black Panther ending of the nucleic in. In the il­lus­tra­tion below acid ), with formula H 5 P 3 O 10, is chemical... Phosphoric acid chlorine changes to chloric and bromine changes to bromic process 3... Water ) than tripolyphosphoric acid, meaning that it can release five protons in basic enough conditions 2. Phosphoric acid will dissolve some of the soil, phosphoric acid is H 3 PO 4 and other acids.

Highest Point In Oldham, Gibson Firebird 1 Reissue, Pasterze Glacier Melting, Origin Of Iron Technology In Africa, Cyclops Onion 0, Jaffa Orange Tree For Sale, Macbook Pro Volume Suddenly Low 2020, Yumearth Organic Lollipops Ingredients, Astor Wines Promo Code,